
水是萬物之源,更是頁巖油氣持久發展的關鍵。
來自 | E&P
編譯 | 張德凱
Mark Wolf 是NOV公司Process and Flow Technologies部門陸地設施的負責人,在水處理技術方面經驗非常豐富。他表示:“Permian Basin的頁巖開發商正在帶領油氣行業走出低潮,但是目前該地區沒有充足的水源以供鉆井、壓裂等作業使用,所以水處理、儲存、運輸、回收利用等問題將會非常關鍵,決定著該地區油氣開發是否能夠成功?!?/span>
水處理公司CH2M 副總裁Michael Dunkel表示:“我相信,油氣開發過程涉及的水處理技術將會迅速發展,成本更低、可持續性更強的方案在今后幾年將會逐漸問世?!?/span>
專業建議,識別廢水處理危險系數

美國一家咨詢顧問公司近日發布了一本300頁的分析報告,主要包括兩方面內容:
1)水利用/處理過程危險系數識別與量化;
2)為了更加安全有效的處理采出水、壓裂用水、其它油田廢水及保護飲用水源,油氣行業對于二類鹽水注入井的使用/依賴趨勢。
目前,關于廢水回注地下的應用與環保法規要求互相矛盾,這些主要由于政治因素引起。該公司從公正及事實的角度出發,根據詳細的地區劃分,從局部、區域及地方角度對廢水回注地下(UIC)法規進行了分析,以相對風險系數對不同操作和設備進行了標識,根據書中所含圖表、目錄,操作人員即可識別危險系數更高、有待進一步詳細調查/消除危險的設備和UIC區域。
這份調查報告中詳細報道了美國主要陸地油田的廢水回注狀況,還進行了代表地區的區域性分析,包括特殊回注狀況、地區地震屬性、油藏危險系數、 技術基礎、法規與訴訟情況、操作連續性、最佳執行方式、地域性降低危險方式以及最新的投資趨勢等。
新型處理工具,降低水處理成本

Veolia公司的ShaleFlow系統是一個經濟、可移動的采出水/回流水處理系統,結構緊湊,便于運輸,采用三拖車配置,隨著作業現場的不斷變化,其位置也可隨之改變,應用靈活性高。ShaleFlow的處理能力達到10000bbl/d,且可處理廢水種類多,可溶性固體廢物含量上限達300000mg/L。該系統將固體顆粒和易結垢的物質水平降低,廢水處理后完全滿足壓裂和完井作業要求。
水處理和重復利用能夠降低新鮮水源的需求量,同時還能達到回收原油、降低采出水處理成本的目的。今年Veolia還推出了另一款產品CoStrip,主要用于去除廢水中的溶解氣體,包括BTEX(苯、甲苯、乙苯和二甲苯)、揮發性有機化合物、CO2和H2S,且該過程完全不需要廢水預處理流程。CoStrip通常作為滿足地表排放標準廢水處理線的一部分使用,對于降低成本具有明顯的作用。若與化學軟化劑配合使用,CoStrip還能有效降低化學藥劑和泥漿成本,并延長反向滲透膜的使用壽命。
加速廢水處理設施建設,降低成本

Victaulic HDPE系統安裝簡便、迅速,Atlas Resources公司的Hamman鹽水處理設置在10天內就完成了安裝,而傳統技術則需要六周
Victaulic聯接系統不含熔融工藝,專用于高密度聚乙烯(HDPE)管件的連接,主要包括小/大直徑聯軸器、適配器、過度轉換器及相關附件。將Victaulic HDPE用于SDR7與21HDPE的管件聯接速率更高,是采用熔融方案連接水/泥漿管線的10倍。Victaulic消除了連接作業中的熔融操作,管件對接更加快速、簡單,且其應用范圍也非常廣,在液體流動管線、輸水、壓裂液儲池、水處理、廢棄鹽水處理以及相關設施建設方面都能發揮巨大作用。
當前,頁巖開發采出水運輸和處理成本已經到達整體開發成本的一半左右,是開發商面臨的最主要降本挑戰。為了控制成本,開發商開始選擇建立獨立的油氣開采和廢水處理設施,取代了第三方水廢水處理公司的加入。Victaulic的HDPE系統能夠幫助開發商更加快速地完成廢水處理設施的建設,同時降低整體安裝成本。Victaulic的聯軸器無論是在垂直方向還是空間受限的區域都能快速鏈接。此外,聯軸器還可以回收重復利用,進一步降低了成本。Victaulic的無熔融工藝管件聯接系統在多處頁巖油藏得到了成功應用,其中包括Permian和Eagle Ford。
頁巖開發回流水處理技術消除鈍化現象

頁巖開發回流水電凝處理(EC)的應用要追溯到2000年左右,EC技術是眾多回流廢水處理工藝的核心。EC具有破乳作用,可溶/不可溶的碳氫化合物、重金屬、懸浮固體顆粒、有機物、細菌的移除率可達98%以上。然而傳統的EC方式都存在著一個明顯的問題—鈍化。鈍化會導致氧化結垢,系統的電極表面也會生成一層鈍化膜,造成顯著的人工成本、能耗增加,降低處理效率和處理量。一旦發生鈍化現象,廢水處理效率會成指數下降,開發商就不得不停機進行清洗或電極更換,成本極高。為了解決該問題,Water Vision推出了專利型ThinCell EC技術,能夠完全避免了鈍化問題的發生。
ThinCell EC采用消耗電極,分解后只會生成常規廢物,電極完全消耗后,只需更換一個新的電極,不會發生設備長時間停機的問題,且電極成本可控。ThinCell EC的清潔和電極更換過程不涉及鋼板等部件的去除操作。鈍化現象的消除穩定了操作所需電流,降低了動力需求和應用標準。ThinCell技術增加了EC廢水處理設備的連續運行時間,降低了設備維修頻率及相關成本、風險。得益于該技術的問世,ThinCell的設備規模得到控制,且具有多種配置,處理流量范圍覆蓋5~500gal/min,靈活性極高。
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REPORT IDENTIFIES AND QUALIFIES SALTWATER RISK FACTORS, TRENDS
The EnergyMakers Advisory Group is publishing a comprehensive 300-page metastudy that identifies and qualifies the complex risk factors and recent trends associated with the oil and gas industry’s operational reliance on Class II saltwater disposal wells for the safe and effective disposal of produced water, fracturing water and approved oilfield liquid wastes as well as protection of U.S. drinking water sources. There is a complex array of conflicting information surrounding use and regulation of underground disposal wells, often with politically driven undertones. In an even-handed, fact-based manner, The EnergyMakers Advisory Group explores these underground injection control (UIC) issues at a macro, regional and local level supported by detailed maps, relative risk weighting factors, and charts and indices allowing operators to identify those assets and UIC formations with higher relative risk that may bear more detailed exploration or risk mitigation. The coverage universe includes a deep dive into each of the leading onshore U.S. basins covering basin and region-specific injection, seismicity, formation health risk indicators, scientific underpinnings, regulatory and litigation landscapes, operations continuity and best practice considerations, region-specific opportunities for risk reduction, and new investment frontiers.
TOOLS REDUCE WATER MANAGEMENT COSTS
Veolia has developed ShaleFlow, a cost-effective mobile system for treatment and reuse of flowback and produced water from hydraulic fracturing operations. This compact, transportable system incorporates proven technologies in a three-trailer configuration with the flexibility to be moved as the field is developed. ShaleFlow can treat up to 10,000 bbl/d and accept a wide range of influent water quality containing up to 300,000 total dissolved solids. The system removes particulates and scale-formers to low levels, generating water quality suitable for reuse in fracturing and completion operations. Water treatment and reuse reduces freshwater demand, recovers oil from produced water and minimizes produced water disposal costs. Another Veolia product released this year is the CoStrip degasifier. CoStrip effectively removes dissolved gases such as BTEX (benzene, toluene, ethylbenzene and xylene), volatile organic compounds, CO2 and H2S without the need for pretreatment. Typically installed as part of a treatment train that enables surface water discharge, CoStrip minimizes the capex and opex costs of the overall system. Its effective operation reduces chemical and sludge costs when paired with chemical softening and extends the life of reverse osmosis membranes.
BUILD SALTWATER DISPOSAL FACILITIES FASTER WITH LOWER OVERALL COSTS
The Victaulic Refuse-to-Fuse joining system for high-density polyethylene (HDPE) pipe is a line of small and large-diameter couplings, fittings, transitions and accessories that can join SDR 7 to 21 HDPE pipe up to 10 times faster than fusion—the common method used in connecting water and slurry HDPE lines. The Victaulic system eliminates the need for fusion, providing a faster, simpler joining method that can be used in a variety of applications including flowlines, water transportation, fracturing ponds, water treatment, saltwater disposal and facility construction. Produced water transportation and disposal costs can represent half of a shale well’s operating expenses and is one of the biggest challenges facing an operator’s bottom line. To put a lid on these costs, operators are building their own production and water disposal facilities instead of relying on third-party waste management companies. Victaulic’s HDPE system is helping shale operators build saltwater disposal facilities faster with lower overall installed costs. The couplings can be easily installed in vertical orientations as well as in tight spaces using simple hand tools and can be reused from site to site. Victaulic’s Refuse-to-Fuse system has been successfully deployed by major operators in several shale plays, including the Permian and Eagle Ford.
SHALE FLOWBACK FLUIDS TREATMENT ELIMINATES PASSIVATION
Electrocoagulation (EC) treatment for shale play well flowback fluids dates back to the early 2000s. Its role is the heartbeat in many flowback fluid treatment processes. It breaks emulsions and reduces insoluble and soluble hydrocarbons, heavy metals, suspended solids, organics and bacteria concentrations at efficiencies exceeding 98%. Traditional EC methods, however, have a problem— passivation. This detrimental challenge causes oxide scale or coating buildup on the system’s electrodes, adding significant costs in manpower, power consumption, efficiency and disposal. Passivation can quickly cause treatment efficiency degradation and shutdown for costly electrode (plate) cleaning or replacement. Water Vision Inc. has developed a proprietary ThinCell EC technology that completely eliminates passivation. The technology uses sacrificial electrodes consisting of a common waste product that are completely consumed and efficiently replenished without costly unit downtime. There is no need for electron/ plate removal for cleaning (acid wash or grinding) or replacement. Passivation elimination preserves the necessary electrical amperage for the cell operation, lowering power requirements and usage. ThinCell technology increases uptime, reduces maintenance and lowers both costs and safety risks. Because of its technology, the ThinCell has a small footprint and is available in a variety of mobile configurations and flow rates from five to greater than 500 gal/ min.
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