
脫水作業是鉆井液無害化處理中的重要環節,絮凝劑則是其中必不可少的化學添加劑,針對普通粉末式絮凝劑溶解慢、易結塊等問題,微珠形式的絮凝劑帶來了有效解決方式。
來自 | E&P
編譯 | 白小明
當前的油氣市場大環境迫使業內許多公司集中精力降低運營成本,努力在本輪持續時間較長的低油價時期保持競爭力。處在整個油氣價值鏈上的所有企業不得不著重評估其產品和服務成本,同時還要努力提高效率,降低油氣采收的盈虧平衡成本。而對水基鉆井液進行有效脫水,則可使作業公司和油服公司在減少鉆井廢棄物的同時,增加鉆井進尺。
鉆井液的脫水是油氣上游行業鉆井作業過程中的一個重要環節,該環節包括從泥漿體系中分離固相、循環利用脫出的水,并使固相廢棄物得到妥善處理。良好的脫水作業有利于提高鉆井液公司和油氣作業公司的一系列運營效率。
水基鉆井液的脫水過程可能產生大量的廢棄物,這些廢棄物必須在開放的泥漿坑或在閉合回路(泥漿不落地設備)中得到處理。閉合系統可連續處理泥漿中的鉆屑,在同等資源條件下,鉆井速度更快、鉆的井更深。使用該系統,可減少鉆井廢棄物產生量和相應的處理成本。
此外,閉合系統的占地面積小,可使油服公司更易達到當地環境法規的要求。泥漿脫水可以提高機械鉆速,改善泥餅的完整性,并減少水和鉆井泥漿添加劑的用量,從而有助于降低總鉆井成本。
脫水化學添加劑
簡言之,脫水過程即從鉆井液體系中分離出固相。該作業通常需要使用化學添加劑來提高脫水設備的整體性能。所使用的化學添加劑包括絮凝劑和助凝劑型聚合物,可通過物理方法改變鉆井液體系的性質,使鉆屑中的小顆粒聚集或“絮凝”在一起,逐漸變得足夠大,以便使用離心機去除。
所添加的聚合物以聚丙烯酰胺(PAM)為基礎,可能帶正電、負電或呈中性。絮凝基于鉆井液中的固相顆粒和PAM聚合物之間的相互作用而產生,而顆粒具有排斥其周圍帶類似電荷顆粒的能力。這些顆粒很難單獨用固控設備去除,因為它們非常小,并且被其自身的電荷半徑包圍,電荷半徑根據固相的類型和數量或水相的特性而不同,所以必須減小電荷半徑來使顆粒絮凝。
添加聚合物可使帶電顆粒彼此接觸,形成具有更高密度、更大體積的顆粒,從而被分離。
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為了有效使小顆粒絮凝,PAM聚合物必須有合適的電荷密度和分子量。隨著不斷改進優化,聚合物與鉆井液中的固體小顆粒之間的相互作用將更充分。BASF油田解決方案事業部的Alcomer 24產品,性能穩定,可用于多個泥漿體系。
聚合物形式
在選擇用于脫水的聚合物時,需要同時評估聚合物優化后的性能以及其與泥漿的兼容性,而選擇更加普遍易購買的產品也同樣很重要。
脫水應用中有兩種主要的聚合物形式:標準粉末和微珠。粉末產品往往具有鋸齒狀,顆粒不均勻,這種不均勻性容易導致結塊、溶解不完全以及與粉塵相關的操作處理問題。因此,使用粉末產品往往難以操作處理。相反,創新的微珠具有均勻的結構,沒有鋸齒狀邊緣,溶解性更好,溶解度更大,方便操作處理。與粉末形式相比,微珠技術在溶解性、流動性等方面有了改善,低粉塵的特性使其易于操作處理,避免了冷凍/解凍的問題。
可用于水基鉆井液作業的微珠產品系列非常多。油田領先的化學添加劑Alcomer 24,已成為了業內的拳頭產品。Alcomer 24采用基于低陰離子聚丙烯酰胺產品的微珠形式,專門設計用于水基鉆井液的絮凝,為閉環處理系統提供良好的產品性能。由于采用微珠形式,該產品比許多粉末形式的競爭產品溶解性更好,在脫水作業中更高效。該產品更容易傾倒,比粉末產品更易配藥。因其獨特的物理形式,作業者在脫水作業中選擇Alcomer 24,可以減少化學品的用量和成本。產品的溶解度和水化時間有突出優勢,同時用量更少。在泥漿體系中使用Alcomer 24后,一些用戶報告稱,化學品的使用量降至了粉末產品用量的一半。
微珠添加劑可采用更少的用量,完成更長井段的鉆進,從而提高作業的效率,降低鉆井成本。一名用戶在現場條件下比較了BASF的產品與其他粉末產品后,發現前者取得的效果令人矚目。使用14袋陰離子粉末產品與6袋碳酸鈣(CaCO3),作業者完成了564米(1,850英尺)進尺,即35米/袋(115英尺/袋)。而使用12袋Alcomer 24和8袋CaCO3,該用戶可以完成792米(2,600英尺)的進尺,即56米/袋(185英尺/袋)。Alcomer 24使用戶取得了額外40%以上的進尺,同時聚合物用量減少了14%。
這種作業效率的提高,連同化學添加劑用量的減少,可使用戶每鉆進1英尺就降低1美元成本。除了這些應用優化,用戶也注意到了Alcomer 24的易操作性和良好的溶解性,整個溶解過程只需要10~15分鐘,而粉末產品需要大約1小時。
The current market climate has forced industry players to focus on reducing their operating costs in an effort to remain competitive during this prolonged downturn. Across the value chain companies have been forced to evaluate the costs of their products and services while simultaneously striving for efficiencies to bring down breakeven extraction costs. The effective dewatering of water-based drilling muds allows operators and service providers to reduce drilling waste while increasing drilling footage, positioning them to remain successful in this competitive industry.
Dewatering of drilling muds is an essential component of upstream drilling operations. The process involves the separation of solids from the mud system, allowing the water to be recycled and the solids to be effectively treated. An adept dewatering operation can facilitate a number of operational efficiencies for fluid companies and oil and gas operators. The process of dewatering water-based drilling muds can produce large amounts of waste that must be treated either in open pits or in a closed loop. When this process is performed in a closed-loop system, it reduces the production of drilling waste and corresponding disposal costs. This system continually treats cuttings in the mud system, the efficiency of which allows wells to be drilled faster and deeper with the same resources. Furthermore, the reduced footprint of these operations can allow oilfield service providers to better comply with state and local environmental regulations. Dewatering the mud can improve penetration rates, improve filter cake integrity and reduce water and drilling fluid chemical use, thus contributing to a reduction in overall well costs.
Dewatering chemicals
In short, the dewatering process involves separating solids from the drilling mud system.Often it is necessary to use chemicals to enhance the overall performance of the dewatering equipment. The chemicals used are both coagulant- and flocculant- type polymers that are able to physically alter the properties to allow small particles from drilling cuttings to agglomerate or “flocculate” together so they are large enough to be removed by a centrifuge. For optimum and efficient solids removal onsite, experimentation is needed to determine the appropriate amount and type of polymer. These polymers are based on polyacrylamide (PAM) that are either positive, negative or neutrally charged. Flocculation is based on the interaction of the drilling mud particles and the PAM polymer. The particles have an electrical charge that repels the like-charged particles surrounding it. These particles are difficult to remove with solids control equipment alone as they are extremely small and are surrounded by their own charge radius, which can vary depending on the type and amount of the solids or the characteristics of the water phase. This charge radius must be reduced to allow the particles to flocculate.
The addition of a polymer-type chemistry allows charged particles to come in contact with each other, forming larger particles that are able to have a higher density and thus are able to be separated.
For a polymer to help flocculate the small particles effectively, the PAM polymer has to have the right charge density and molecular weight. As these aspects are more optimized, the polymer will interact more robustly with the solid small particles in the drilling mud. Alcomer 24 from BASF’s Oilfield Solutions Business has been designed to offer a large, robust performance over several mud systems.
Polymer forms
When selecting polymer for use in dewatering, along with evaluating optimized performance and compatibility with the muds it is important to also use products that are easy for an operator to use. There are two main types of polymer form that are used in dewatering applications: standard powder and microbeads. Powder products tend to be jagged with nonuniform particles. This nonuniform nature leads to clumping, incomplete dissolution and handling concerns related to dust particles. Powders are therefore often considered hard to handle in applications. Alternatively, the innovative microbeads have a uniform structure with no jagged edges, which can allow better dissolution, better solubility and better handling. Microbead technology offers improvement over powder forms in solubility, pourability, ease of handling with low dust and avoidance of freeze/thaw issues.
There is a wide range of bead products available for use in water-based drilling operations. A leading chemistry in the field, Alcomer 24 has become an industry mainstay. A low-anionic polyacrylamide-based product in microbead form, Alcomer 24 has been specifically designed to flocculate water-based drilling muds and provide better performance in closed-loop systems. As a result of its microbead form, the product offers more solubility than many powder competitors, which makes it more effective in dewatering operations. The product is more easily poured, allowing it to be more effectively dosed than powders, where clumping can cause handling challenges. As a result of its physical form, the selection of Alcomer 24 in dewatering applications can reduce overall chemical usage and expenditure. The product solubility and hydration time leads to superior performance in application, which can allow fluids companies to reduce flocculant chemical volumes. Through effective handling, customers can achieve proper chemical dosing and reduce potential wasted polymer from product clumping. When a mud system is optimized with Alcomer 24, some customers report a usage rate of half vs. the competitive powder offerings.
The additive can allow a longer well to be drilled with less product, thereby improving operational efficiency and reducing drilling costs. One customer saw impressive results in field conditions when comparing the BASF product against a competitor’s powder offering. Using 14 bags of a competitor’s anionic powder along with six bags of calcium carbonate (CaCO3), the customer drilled 564 m (1,850 ft), or 35 m/bag (115 ft/bag). Using 12 bags of Alcomer 24 and eight bags of CaCO3, this same customer was able to drill 792 m (2,600 ft), or 56 m/bag (185 ft/bag). Alcomer 24 permitted this customer to drill a 40% longer well with a 14% decrease in polymer volume. This increase in operational efficiency, coupled with a decrease in chemical dosage, allowed the customer to decrease costs on a dollar-per-foot basis. In addition to these application improvements, the customer noted the product’s ease of handling and improved solubility, with Alcomer 24 taking 10 minutes to 15 minutes vs. the powder product, which took about one hour.
Through the use of high-performance PAM products such as Alcomer 24, oilfield service providers can achieve operational efficiencies and reduce costs, helping them to compete in the current market climate.
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